Coquandite
A valid IMA mineral species
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About Coquandite
Formula:
Sb6+xO8+x(SO4)(OH)x(H2O)1- x (x = 0.3)
Originally assumed to be (SbO)6(SO4)O2.H2O.
Colour:
Colorless
Lustre:
Adamantine
Hardness:
3 - 4
Specific Gravity:
5.78 (Calculated)
Crystal System:
Triclinic
Name:
In honour of the French scientist Henri Coquand (1811/13-1881), Professor of geology and mineralogy, who carried out extensive studies of the antimony deposits of Tuscany between 1842 and 1849.
This page provides mineralogical data about Coquandite.
Unique Identifiers
Mindat ID:
1125
Long-form identifier:
mindat:1:1:1125:5
GUID
(UUID V4):
(UUID V4):
f6316d5d-7814-4210-bb6a-42297773c5be
IMA Classification of Coquandite
Approved
IMA Formula:
Sb3+6+xO8+x(SO4)(OH)x(H2O)1-x (x = 0.3)
Approval year:
1991
First published:
1992
Classification of Coquandite
7.DE.35
7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
E : With only medium-sized cations; unclassified
7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
E : With only medium-sized cations; unclassified
30.1.18.1
30 : ANHYDROUS SULFATES CONTAINING HYDROXYL OR HALOGEN
1 : (AB)m(XO4)pZq, where m:p>2:1
30 : ANHYDROUS SULFATES CONTAINING HYDROXYL OR HALOGEN
1 : (AB)m(XO4)pZq, where m:p>2:1
25.8.2
25 : Sulphates
8 : Sulphates of Sb, V, Cr and U
25 : Sulphates
8 : Sulphates of Sb, V, Cr and U
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Cqd | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Coquandite
Adamantine
Transparency:
Transparent, Translucent
Colour:
Colorless
Streak:
White
Hardness:
3 - 4 on Mohs scale
Tenacity:
Flexible
Cleavage:
None Observed
Density:
5.78 g/cm3 (Calculated)
Optical Data of Coquandite
Type:
Biaxial (+)
Dispersion:
r < v strong
Comments:
Small size and high RI made optical determinations difficult.
Chemistry of Coquandite
Mindat Formula:
Sb6+xO8+x(SO4)(OH)x(H2O)1- x (x = 0.3)
Originally assumed to be (SbO)6(SO4)O2.H2O.
Originally assumed to be (SbO)6(SO4)O2.H2O.
Elements listed:
Crystallography of Coquandite
Crystal System:
Triclinic
Class (H-M):
1 - Pinacoidal
Space Group:
P1
Cell Parameters:
a = 11.4292(5) Å, b = 29.772(1) Å, c = 11.2989(5) Å
α = 91.152(3)°, β = 119.266(4)°, γ = 92.624(3)°
α = 91.152(3)°, β = 119.266(4)°, γ = 92.624(3)°
Ratio:
a:b:c = 0.384 : 1 : 0.38
Unit Cell V:
3,346.44 ų (Calculated from Unit Cell)
Z:
10
Morphology:
Tabular crystals, lamellar, fibers. Elongated along [001] and flattened on {010}.
Twinning:
Polysynthetic twinning with (010) as the twin plane.
Crystal Structure
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Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0020507 | Coquandite | Bindi L, Biagioni C, Ceccantini L, Batoni M, Menchetti S (2014) Coquandite, Sb6+xO8+x(SO4)(OH)x*(H2O)1-x (x=0.3), from the Cetine mine, Tuscany, Italy: crystal structure and revision of the chemical formula Mineralogical Magazine 78 871-888 | 2014 | Cetine mine, Tuscany, Italy | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
3.3006 Å | (100) |
3.0573 Å | (76) |
14.8527 Å | (64) |
3.1164 Å | (51) |
3.0863 Å | (45) |
2.8151 Å | (40) |
3.1939 Å | (28) |
3.2010 Å | (27) |
2.8405 Å | (26) |
2.7095 Å | (25) |
Comments:
Data from Bindi et al. (2014).
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Stage 7: Great Oxidation Event | <2.4 |
47a : [Near-surface hydration of prior minerals] | |
47b : [Sulfates and sulfites] | |
47d : [Arsenates, antimonates, selenates, bismuthinates] |
Type Occurrence of Coquandite
Co-Type Localities:
General Appearance of Type Material:
Spheroidal knobs of silky fibres or, rarely, as tiny transparent colourless lamellar crystals on stibnite.
Place of Conservation of Type Material:
National Museum of Natural History, (Smithsonian Institution), Washington D.C., USA.
Museums of Natural History of the Universities of Florence and Pisa, Italy (catalogue numbers l761/RI and 8800, respectively).
Museums of Natural History of the Universities of Florence and Pisa, Italy (catalogue numbers l761/RI and 8800, respectively).
Geological Setting of Type Material:
Oxidized stibnite deposit
Associated Minerals at Type Locality:
Reference:
Sabelli, C., Orlandi, P., Vezzalini, G. (1992) Coquandite, Sb6O8(SO4)·H2O, a new mineral from Pereta, Tuscany, Italy, and two other localities. Mineralogical Magazine: 56: 599-603.
Synonyms of Coquandite
Other Language Names for Coquandite
German:Coquandit
Spanish:Coquandita
Common Associates
Associated Minerals Based on Photo Data:
16 photos of Coquandite associated with Stibnite | Sb2S3 |
10 photos of Coquandite associated with Sulphur | S8 |
5 photos of Coquandite associated with Stibiconite | Sb3+Sb5+2O6(OH) |
4 photos of Coquandite associated with Quartz | SiO2 |
3 photos of Coquandite associated with Klebelsbergite | Sb4O4(SO4)(OH)2 |
1 photo of Coquandite associated with Halotrichite | FeAl2(SO4)4 · 22H2O |
Related Minerals - Strunz-mindat Grouping
7.DE. | Magnesioalterite | Mg2Fe3+4(SO4)4(C2O4)2(OH)4 · 17H2O |
7.DE. | Fabritzite | Zn9(SO4)2(OH)12Cl2 · 6H2O |
7.DE. | Cossaite | (Mg0.5,◻)Al6(SO4)6(HSO4)F6 · 36H2O |
7.DE. | Downsite | K2(MoO3)3(SO4) · 4H2O |
7.DE. | Liangjunite | K2(Mo2O5)(SO4)2 · 3H2O |
7.DE.05 | Mangazeite | Al2(SO4)(OH)4 · 3H2O |
7.DE.10 | UKI-1975-(SO:AlCu) | (Cu, Al, SO4, H2O) |
7.DE.10 | Carbonatecyanotrichite | Cu4Al2(CO3,SO4)(OH)12 · 2H2O |
7.DE.10 | Cyanotrichite | Cu4Al2(SO4)(OH)12 · 2H2O |
7.DE.15 | Schwertmannite | Fe3+16(OH,SO4)12-13O16 · 10-12H2O |
7.DE.20 | Tlalocite | Cu10Zn6(Te6+O4)2(Te4+O3)(OH)25Cl · 27H2O |
7.DE.25 | Utahite | MgCu4Zn2Te6+3O14(OH)4 · 6H2O |
7.DE.40 | Osakaite | Zn4(SO4)(OH)6 · 5H2O |
7.DE.42 | Alterite | Zn2Fe3+4(SO4)4(C2O4)2(OH)4 · 17H2O |
7.DE.45 | Barrotite | Cu9Al(HSiO4)2[(SO4)(HAsO4)0.5](OH)12 · 8H2O |
7.DE.45 | Wilcoxite | MgAl(SO4)2F · 17H2O |
7.DE.47 | Tiberiobardiite | {Cu9Al[SiO3(OH)]2(OH)12(H2O)6}(SO4)1.5 · 10H2O |
7.DE.50 | Bouškaite | (MoO2)2O(SO3OH)2(H2O)4 |
7.DE.50 | Stanleyite | (V4+O)(SO4) · 6H2O |
7.DE.57 | Khangalasite | Fe(SO4)(OH) · 2H2O |
7.DE.60 | Hydrobasaluminite | Al4(SO4)(OH)10 · 12-36H2O |
7.DE.62 | Volaschioite | Fe4(SO4)O2(OH)6 · 2H2O |
7.DE.65 | Zaherite | Al12(SO4)5(OH)26 · 20H2O |
7.DE.75 | Camérolaite | Cu6Al3(OH)18(H2O)2[Sb(OH)6](SO4) |
Fluorescence of Coquandite
None observed
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Coquandite
mindat.org URL:
https://www.mindat.org/min-1125.html
Please feel free to link to this page.
Please feel free to link to this page.
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References for Coquandite
Reference List:
Sabelli, C., Orlandi, P., Vezzalini, G. (1992) Coquandite, Sb6O8(SO4)H2O, a new mineral from Pereta, Tuscany, Italy, and two other localities. Mineralogical Magazine, 56 (385) 599-603 doi:10.1180/minmag.1992.056.385.16
Localities for Coquandite
Locality List




All localities listed without proper references should be considered as questionable.
Greece | |
| Rieck et al. (2018) |
Italy (TL) | |
| Sabelli et al. (1992) |
| Orlandi (1997) +1 other reference |
| Lapis Magazine Vol 6.1993 Page 22 +1 other reference |
Japan | |
| specimens seen at Kyoto show |
Luxembourg | |
| Filella et al. (2009) |
Portugal | |
| Roper et al. (2015) |
Romania | |
| Gabor Koller specimens |
collected: Gábor Koller | |
Gábor Koller collection (EDS- and PXRD-analysed by Sándor Szakáll and Béla Fehér) | |
USA (TL) | |
| Sabelli et al. (1992) |
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Lucky Knock Mine, Okanogan County, Washington, USA