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Cobalt(II) chlorate

From Wikipedia, the free encyclopedia
Cobalt(II) chlorate
Names
Other names
cobaltous chlorate
Identifiers
3D model (JSmol)
ChemSpider
  • InChI=1S/2ClHO3.Co/c2*2-1(3)4;/h2*(H,2,3,4);/q;;+2/p-2 checkY
    Key: IQYVXTLKMOTJKI-UHFFFAOYSA-L checkY
  • InChI=1S/2ClHO3.Co/c2*2-1(3)4;/h2*(H,2,3,4);/q;;+2/p-2
    Key: IQYVXTLKMOTJKI-NUQVWONBAD
  • Key: IQYVXTLKMOTJKI-UHFFFAOYSA-L
  • [Co+2].[O-]Cl(=O)=O.[O-]Cl(=O)=O
Properties
Co(ClO3)2
Molar mass 225.9 g/mol
Appearance deliquescent pink crystals
Melting point 50 °C (hexahydrate)[1]
soluble in water
Related compounds
Other cations
nickel chlorate

iron chlorate

Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Cobalt(II) chlorate is a chemical compound with the formula Co(ClO3)2. It is an oxidant, as are all chlorates.

Preparation

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Cobalt(II) chlorate is formed by a double displacement reaction between cobalt(II) sulfate and barium chlorate, barium sulfate precipitates and cobalt chlorate can be crystallized out of the filtrate:[2]

CoSO4 + Ba(ClO3)2 → BaSO4 + Co(ClO3)2

It is also possible to make it by the reaction of any chlorate with a cobalt(II) salt, however the pure product is harder to separate.

References

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  1. ^ rthur Messinger Comey (1921). A Dictionary of Chemical Solubilities: Inorganic. Macmillan Company. p. 225.
  2. ^ Xie, Gaoyang; et al. Series of Inorganic Chemistry. Volume IX - Manganese group, iron group and platinum group. Science Press, 1996. pp 303. Cobalt halates and perhalates. ISBN 9787030305459 (in Chinese)