Bakar monosulfid

Bakar monosulfid
	Bakar sulfid
Drugi nazivi	Kovelit; Bakar(II) sulfid; Kupri sulfid
Identifikacija
CAS registarski broj	1317-40-4
PubChem	14831
ChemSpider	14145
RTECS registarski broj toksičnosti	GL8912000
Jmol-3D slike	Slika 1
SMILES
	[Cu]=S
InChI
	InChI=1S/Cu.S ; Kod: BWFPGXWASODCHM-UHFFFAOYSA-N InChI=1/Cu.S/rCuS/c1-2; Kod: BWFPGXWASODCHM-BLKBWTQCAT
Svojstva
Molekulska formula	CuS
Molarna masa	95,611 g/mol
Agregatno stanje	crni prah ili grumeni
Gustina	4,76 g/cm3
Tačka topljenja	iznad 500 °C (razlaže se )
Rastvorljivost u vodi	0,000033 g/100 mL (18 °C)
Ksp	1,27 x 10-36
Rastvorljivost	rastvoran u HNO3, NH4OH, KCN ; nerastvoran u HCl, H2SO4
Indeks prelamanja (nD)	1.45
Struktura
Kristalna rešetka/struktura	heksagonalna
Srodna jedinjenja
Drugi anjoni	Bakar(II) oksid
Drugi katjoni	cink sulfid
	(šta je ovo?) (verifikuj) ; Ukoliko nije drugačije napomenuto, podaci se odnose na standardno stanje (25 °C, 100 kPa) materijala
	Infobox references

Bakar monosulfid je hemijsko jedinjenje bakra i sumpora. Ono se javlja u prirodi kao crni indigo plavi mineral kovelit. On je umereni provodnik struje.^[5] Crni koloidni precipitat CuS se formira kad se vodonik sulfid, H₂S, provodi kroz rastvore Cu(II) soli^[6] On je jedan od brojnih binarnih jedinjenja bakra i sumpora (bakar sulfida). On potencijalno može da služi kao katalizator^[7] and photovoltaics.^[8]

Reference

↑ Li Q, Cheng T, Wang Y, Bryant SH (2010). „PubChem as a public resource for drug discovery.”. Drug Discov Today 15 (23-24): 1052-7. DOI:10.1016/j.drudis.2010.10.003. PMID 20970519. edit
↑ Evan E. Bolton, Yanli Wang, Paul A. Thiessen, Stephen H. Bryant (2008). „Chapter 12 PubChem: Integrated Platform of Small Molecules and Biological Activities”. Annual Reports in Computational Chemistry 4: 217-241. DOI:10.1016/S1574-1400(08)00012-1.
↑ Hettne KM, Williams AJ, van Mulligen EM, Kleinjans J, Tkachenko V, Kors JA. (2010). „Automatic vs. manual curation of a multi-source chemical dictionary: the impact on text mining”. J Cheminform 2 (1): 3. DOI:10.1186/1758-2946-2-3. PMID 20331846. edit
↑ Blachnik R., Müller, A. (2000). „The formation of Cu₂S from the elements I. Copper used in form of powders”. Thermochimica Acta 361 (1–2): 31–52. DOI:10.1016/S0040-6031(00)00545-1
↑ Wells A.F. (1962) Structural Inorganic Chemistry 3d edition Oxford University Press
↑ Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd izd.). Oxford: Butterworth-Heinemann. ISBN 0080379419.
↑ Kuchmii S.Y., Korzhak A.V., Raevskaya A.E.,Kryukov A.I. (2001). „Catalysis of the Sodium Sulfide Reduction of Methylviologene by CuS Nanoparticles”. Theoretical and Experimental Chemistry (New York: Springer) 37 (1): 36–41. DOI:10.1023/A:1010465823376.
↑ Mane R.S., Lokhande C.D. (June 2000). „Chemical deposition method for metal chalcogenide thin films”. Materials Chemistry and Physics 65 (1): 1–31. DOI:10.1016/S0254-0584(00)00217-0.

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Spoljašnje veze

Portal Hemija

[1] Li Q, Cheng T, Wang Y, Bryant SH (2010). „PubChem as a public resource for drug discovery.”. Drug Discov Today 15 (23-24): 1052-7. DOI:10.1016/j.drudis.2010.10.003. PMID 20970519. edit

[2] Evan E. Bolton, Yanli Wang, Paul A. Thiessen, Stephen H. Bryant (2008). „Chapter 12 PubChem: Integrated Platform of Small Molecules and Biological Activities”. Annual Reports in Computational Chemistry 4: 217-241. DOI:10.1016/S1574-1400(08)00012-1.

[3] Hettne KM, Williams AJ, van Mulligen EM, Kleinjans J, Tkachenko V, Kors JA. (2010). „Automatic vs. manual curation of a multi-source chemical dictionary: the impact on text mining”. J Cheminform 2 (1): 3. DOI:10.1186/1758-2946-2-3. PMID 20331846. edit

[Blachnik-4] Blachnik R., Müller, A. (2000). „The formation of Cu₂S from the elements I. Copper used in form of powders”. Thermochimica Acta 361 (1–2): 31–52. DOI:10.1016/S0040-6031(00)00545-1

[Wells-5] Wells A.F. (1962) Structural Inorganic Chemistry 3d edition Oxford University Press

[Greenwood-6] Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd izd.). Oxford: Butterworth-Heinemann. ISBN 0080379419.

[7] Kuchmii S.Y., Korzhak A.V., Raevskaya A.E.,Kryukov A.I. (2001). „Catalysis of the Sodium Sulfide Reduction of Methylviologene by CuS Nanoparticles”. Theoretical and Experimental Chemistry (New York: Springer) 37 (1): 36–41. DOI:10.1023/A:1010465823376.

[8] Mane R.S., Lokhande C.D. (June 2000). „Chemical deposition method for metal chalcogenide thin films”. Materials Chemistry and Physics 65 (1): 1–31. DOI:10.1016/S0254-0584(00)00217-0.

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