Main Characters
Ash Ketchum | Pikachu | Misty | Brock | Tracey Sketchit | May | Max | Dawn | Iris | Cilan | Serena | Clemont | Bonnie | Rotom Pokédex | Kiawe | Lillie | Mallow | Sophocles | Lana | Goh | Chloe Cerise | Liko | Roy | Dot
Rising Volt Tacklers
Professor Friede | Orla | Mollie | Murdock | Ludlow | Captain Pikachu | Liko | Roy | Dot

Professors
Professor Oak | Professor Elm | Professor Birch | Professor Rowan | Professor Juniper | Professor Sycamore | Professor Kukui | Professor Amaranth | Professor Burnet | Professor Cerise | Professor Magnolia | Professor Sonia | Professor Friede

Allies
Gary Oak | Officer Jenny | Nurse Joy | Jimmy | Marina | Ritchie | Casey | Sakura | Drew | Solana | Zoey | Kenny | Barry | Candice | Looker | Riley | Lyra | Tobias | Bianca | Georgia | N | Rood | Danika | Quillon | Anthea and Concordia | Sawyer | Alain | Mairin | Aria | Tierno | Shauna | Trevor | Gladion | Guzma | Hapu | Wicke

Relatives
Delia Ketchum | Johanna | Grace | Samson Oak | Lusamine | Mohn

Other Characters
Giselle | Duplica | Florinda Showers | Harrison | Cheryl | Ippei

Champions
Lance | Steven Stone | Cynthia | Alder (formerly) | Iris | Diantha | Ash Ketchum | Leon

Rising Volt Tacklers
Friede | Orla | Mollie | Murdock | Ludlow | Captain Pikachu

Movie Characters
Main anime timeline
Corey | Neesha | Fergus | Melody | Diana | Towa | Bianca | Sir Aaron | Rafe | Jack Walker | Alice | Newton Graceland | Maury | Eric Prince Raleigh | Princess Kimia | Karl | Tatsuki | Callahan | Latias | Latios | Lucario | Sheena | Kevin | Rowena | Baraz | Meray | Toren | Carlita | Damos | Risa | Koko
Pokémon the Movie: I Choose You! timeline
Ash Ketchum | Sorrel | Verity | Risa | Margo | Callahan | Oliver | Mia | Kellie | Toren | Harriet | Koko

Main Pokémon
Pikachu | Bulbasaur | Charizard | Squirtle | Eevee | Butterfree | Sceptile | Buizel | Lucario | Snivy | Greninja | Incineroar | Psyduck | Vulpix | Scyther | Blaziken | Skitty | Piplup | Pachirisu | Sylveon | Chespin | Fennekin | Sparky | Riolu | Cinderace

Legendary/Mythical Pokémon
Mewtwo | Mew | Lugia | Ho-Oh | Entei | Celebi | Kyogre | Latias | Latios | Deoxys | Dialga | Palkia | Giratina | Cresselia | Darkrai | Shaymin | Arceus | Zekrom | Reshiram | Kyurem | Meloetta | Diancie | Zarude | Zacian and Zamazenta | Enamorus

Other Pokémon
Ivysaur | Venusaur | Blastoise | Raichu | Jigglypuff | Gyarados | Ditto | Snorlax | Pichu | Gardevoir | Metagross | Munchlax | Oshawott | Zoroark | Inkay | Malamar | Wyrdeer | Ursaluna | Basculegion | Sneasler | Hisuian Braviary

Groups and Organizations
Ash's Friends | Pokémon Trainers