Abstract
By using the new fluorometric method of determination of the total selenium (Σ Se), Se (IV) and Se (VI), the content of selenium in sea weter was determined in the western North Pacific. Results showed that the content ofΣ Se in surface water ranged from 0.06 to 0.12μg l−1, while in deeper layers, the content increased to 0.20μg l−1. It was found that Se (IV) showed rather uniform distribution with depth, while Se (VI) increased with depth to about three times that in the surface. The ratio of Se (IV) to theΣ Se ranged from 0.5 to 0.8 in the surface and 0.4 to 0.6 in the deep. The coexistence of the hexa- and tetravalent ions of selenium was confirmed both in surface and deep layers. Some results of observations on the content of selenium in the coastal areas of Japan were also reported.
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References
Chau, Y. K. andJ. P. Riley (1965): The determination of selenium in sea water, silicates and marine organism. Anal. Chim. Acta,33, 36–49.
Gohda, S. (1972): Activation analysis of arsenic, cupper and antimony in sea water. Bull. Chem. Soc. Japan,45, 1704–1708.
Gohda, S. (1974): The content and the oxidation state of arsenic and antimony in coastal water of Japan. J. Oceanogr. Soc. Japan,30, 163–167.
Goldschmidt, V. M. andL. W. Strock (1935): Zur Geochemie des Selens II. Ges. d. Wiss. Nachrichten. Math.-Phys. Kl. Fachgr. IV, N. F. Bd. I, Nr. 11, 123–142.
Hiraki, K., O. Yoshii, H. Hirayama, Y. Nishikawa andT. Shigematsu (1973): Fluorometric determination of selenium in sea water. Japan Analyst,22, 712–718 (in Japanese).
Ishibashi, M., T. Shigematsu andY. Nagasawa (1935): Determination of selenium in sea water. Rec. Oceanogr. Wks. Japan, New Ser.,1, 44–48.
Lott, P. F., P. Cuker, G. Muriber andJ. Solga (1963): 2, 3-Diaminonaphthalene as a reagent for the determination of milligram to submicrogram amounts of selenium. Anal. Chem.,35, 1159–1163.
Miyake, Y. andS. Tsunogai (1963): Evaporation of iodine from the ocean. J. Geophys. Res.,68, 3689–3699.
Parker, C. A. andL. G. Harvey (1962): Luminescence of some piazselenols; a new fluorimetric reagent for selenium. Analyst,87, 558–565.
Schutz, D. F. andK. K. Turekian (1965): The investigation of the geographical and vertical distribution of several trace elements in sea water using neutron activation analysis. Geochim. Cosmochim. Acta,29, 259–313.
Shimoishi, Y. (1973): Determination of selenium in sea water by gaschromatography with electron capture detection. Anal. Chim. Acta,64, 465–468.
Sillén, L. G. (1959): The physical chemistry of sea water.In, Oceanography, ed. byM. Sears, AAAS, Wash. D. C., pp. 549–582.
Sugawara, K., K. Terada, S. Kanamori andS. Okabe (1962): On different distribution of calcium, strontium, iodine, arsenic and molybdenum in the Northwestern Pacific, Indian and Antarctic Ocean. J. Earth Sci., Nagoya Univ.,10, 33–50.
Sugawara, K. andS. Kanamori (1964): The spectrophotometric determination of trace amount of arsenate and arsenite in natural water with special reference to phosphate determination. Bull. Chem. Soc. Japan,37, 1358–1363.
Sugimura Y. and Y.Suzuki (1976): A new fluorometric method of analysis of selenium in sea water, J. Oceanogr. Soc. Japan (in press).
Wattenberg, H. (1938): Selen im Meerwasser. Z. Anorg. Chem.,236, 339.
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Sugimura, Y., Suzuki, Y. & Miyake, Y. The content of selenium and its chemical form in sea water. Journal of the Oceanographical Society of Japan 32, 235–241 (1976). https://doi.org/10.1007/BF02107126
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DOI: https://doi.org/10.1007/BF02107126